Viscometer

A viscometer (also called viscosimeter) is an instrument used to measure the viscosity of a fluid. For liquids with viscosities which vary with flow conditions, an instrument called a rheometer is used. Viscometers only measure under one flow condition.

In general, either the fluid remains stationary and an object moves through it, or the object is stationary and the fluid moves past it. The drag caused by relative motion of the fluid and a surface is a measure of the viscosity. The flow conditions must have a sufficiently small value of Reynolds number for there to be laminar flow.

At 20.00 degrees Celsius the viscosity of water is 1.002 mPa·s and its kinematic viscosity (ratio of viscosity to density) is 1.0038 mm²/s. These values are used for calibrating certain types of viscometer.

Standard laboratory viscometers for liquids

File:Ubbelohde.jpg

Ostwald viscometers measure the viscosity of a fluid with a known density.

U-tube viscometers

These devices also are known as glass capillary viscometers or Ostwald viscometers, named after Wilhelm Ostwald. Another version is the Ubbelohde viscometer, which consists of a U-shaped glass tube held vertically in a controlled temperature bath. In one arm of the U is a vertical section of precise narrow bore (the capillary). Above this is a bulb, with it is another bulb lower down on the other arm. In use, liquid is drawn into the upper bulb by suction, then allowed to flow down through the capillary into the lower bulb. Two marks (one above and one below the upper bulb) indicate a known volume. The time taken for the level of the liquid to pass between these marks is proportional to the kinematic viscosity. Most commercial units are provided with a conversion factor, or can be calibrated by a fluid of known properties. The time required for the test liquid to flow through a capillary of a known diameter of a certain factor between two marked points is measured. By multiplying the time taken by the factor of the viscometer, the kinematic viscosity is obtained.

Such viscometers are also classified as direct flow or reverse flow. Reverse flow viscometers have the reservoir above the markings and direct flow are those with the reservoir below the markings. Such classifications exists so that the level can be determined even when opaque or staining liquids are measured, otherwise the liquid will cover the markings and make it impossible to gauge the time the level passes the mark. This also allows the viscometer to have more than 1 set of marks to allow for an immediate timing of the time it takes to reach the 3rd mark, therefore yielding 2 timings and allowing for subsequent calculation of Determinability to ensure accurate results.

Falling sphere viscometers

File:Terminal velocity.svg

Creeping flow past a sphere.

Stokes' law is the basis of the falling sphere viscometer, in which the fluid is stationary in a vertical glass tube. A sphere of known size and density is allowed to descend through the liquid. If correctly selected, it reaches terminal velocity, which can be measured by the time it takes to pass two marks on the tube. Electronic sensing can be used for opaque fluids. Knowing the terminal velocity, the size and density of the sphere, and the density of the liquid, Stokes' law can be used to calculate the viscosity of the fluid. A series of steel ball bearings of different diameter is normally used in the classic experiment to improve the accuracy of the calculation. The school experiment uses glycerine as the fluid, and the technique is used industrially to check the viscosity of fluids used in processes. It includes many different oils, and polymer liquids such as solutions.

In 1851, George Gabriel Stokes derived an expression for the frictional force (also called drag force) exerted on spherical objects with very small Reynolds numbers (e.g., very small particles) in a continuous viscous fluid by changing the small fluid-mass limit of the generally unsolvable Navier-Stokes equations:

\[F = 6 \pi r \eta v \,\]

where:

• \(F\) is the frictional force,
• \(r\) is the radius of the spherical object,
• \(\eta\) is the fluid viscosity, and
• \(v\) is the particle's velocity.

If the particles are falling in the viscous fluid by their own weight, then a terminal velocity, also known as the settling velocity, is reached when this frictional force combined with the buoyant force exactly balance the gravitational force. The resulting settling velocity (or terminal velocity) is given by:

\[V_s = \frac{2}{9}\frac{r^2 g (\rho_p - \rho_f)}{\mu}\]

where:

• V_s is the particles' settling velocity (m/s) (vertically downwards if \(\rho_p>\rho_f\), upwards if \(\rho_p<\rho_f\)),
• \(r\) is the Stokes radius of the particle (m),
• g is the gravitational acceleration (m/s²),
• ρ_p is the density of the particles (kg/m³),
• ρ_f is the density of the fluid (kg/m³), and
• \(\mu\) is the (dynamic) fluid viscosity (Pa s).

Note that Stokes flow is assumed, so the Reynolds number must be small.

A limiting factor on the validity of this result is the Roughness of the sphere being used.

A modification of the straight falling sphere viscometer is a rolling ball viscometer which times a ball rolling down a slope whilst immersed in the test fluid. This can be further improved by using a patented V plate which increases the number of rotations to distance traveled, allowing smaller more portable devices. This type of device is also suitable for ship board use. Currently, new equipment is developed for viscosity measurements. This equipment is survismeter and not only measures viscosity only but along with viscosity, it also measures surface tension, interfacial tension, wetting coefficient with high accuracy and precision. The survismeter also measures a new parameter which is noted as friccohesity. The friccohesity establishes a interface between the cohesive forces and the frictional forces within the similar or dissimilar molecules, dispersed in desired medium.

Falling Piston Viscometer

Norcross In-Tank Viscometer

Also known as Norcross viscometer due to inventor, Austin Norcross. The principle of viscosity measurement in this rugged and sensitive industrial device is based on piston and cylinder assembly. The piston is periodically raised by an air lifting mechanism, drawing the material being measured down through the clearance(gap)between the piston and the wall of the cylinder into the space which is formed below the piston as it is raised. The assembly is then typically held up for a few seconds, then allowed to fall by gravity, expelling the sample out through the same path that it entered, creating a shearing effect on the measured liquid, which makes this viscometer particularly sensitive and good for measuring certain thixotropic liquids. The time of fall is a measure of viscosity, with the clearance between the piston and inside of the cylinder forming the measuring orifice. The viscosity controller measures the time of fall (Time-of-fall seconds being the measure of viscosity) and displays the resulting viscosity value. Controller can calibrate time-of-fall value to cup seconds(known efflux cup), SSU or centipoise.
Industrial use is popular due to simplicity, repeatability, low maintenance and longevity. This type of measurement is not affected by flow rate or external vibrations. The principle of operation can be adopted for many different conditions, making it ideal for process control environments.

Oscillating Piston Viscometer

Sometimes referred to as Electromagnetic Viscometer or EMV viscometer, was invented at Cambridge Viscosity (Formally Cambridge Applied Systems) in 1986. The sensor (see figure below) comprises a measurement chamber and magnetically influenced piston. Measurements are taken whereby a sample is first introduced into the thermally controlled measurement chamber where the piston resides. Electronics drive the piston into oscillatory motion within the measurement chamber with a controlled magnetic field. A shear stress is imposed on the liquid (or gas) due to the piston travel and the viscosity is determined by measuring the travel time of the piston. The construction parameters for the annular spacing between the piston and measurement chamber, the strength of the electromagnetic field, and the travel distance of the piston are used to calculate the viscosity according to Newton’s Law of Viscosity.

Oscillating Piston Viscometer Schematic View

The Oscillating Piston Viscometer technology has been adapted for small sample viscosity and micro-sample viscosity testing in laboratory applications. It has also been adapted to measure high pressure viscosity and high temperature viscosity measurements in both laboratory and process environments. The viscosity sensors have been scaled for a wide range of industrial applications such as small size viscometer s for use in compressors and engines, flow-through viscometer s for dip coating processes, in-line viscometer s for use in refineries, and hundreds of other applications. Improvements in sensitivity from modern electronics, is stimulating a growth in Oscillating Piston Viscometer popularity with academic laboratories exploring gas viscosity.

Vibrational viscometers

Vibrational viscometers date back to the 1950s Bendix instrument, which is of a class that operates by measuring the damping of an oscillating electromechanical resonator immersed in a fluid whose viscosity is to be determined. The resonator generally oscillates in torsion or transversely (as a cantilever beam or tuning fork). The higher the viscosity, the larger the damping imposed on the resonator. The resonator's damping may be measured by one of several methods:

1. Measuring the power input necessary to keep the oscillator vibrating at a constant amplitude. The higher the viscosity, the more power is needed to maintain the amplitude of oscillation.
2. Measuring the decay time of the oscillation once the excitation is switched off. The higher the viscosity, the faster the signal decays.
3. Measuring the frequency of the resonator as a function of phase angle between excitation and response waveforms. The higher the viscosity, the larger the frequency change for a given phase change.

The vibrational instrument also suffers from a lack of a defined shear field, which makes it unsuited to measuring the viscosity of a fluid whose flow behaviour is not known before hand.

Vibrating viscometers are rugged industrial systems used to measure viscosity in the process condition. The active part of the sensor is a vibrating rod. The vibration amplitude varies according to the viscosity of the fluid in which the rod is immersed. These viscosity meters are suitable for measuring clogging fluid and high-viscosity fluids, including those with fibers (up to 1,000 Pa·s). Currently, many industries around the world consider these viscometers to be the most efficient system with which to measure the viscosities of a wide range of fluids; by contrast, rotational viscometers require more maintenance, are unable to measure clogging fluid, and require frequent calibration after intensive use. Vibrating viscometers have no moving parts, no weak parts and the sensitive part is very small. Even very basic or acidic fluids can be measured by adding a protective coating or by changing the material of the sensor to a material such as 316L, SUS316, or enamel

Rotational viscometers

Rotational viscometers use the idea that the torque required to turn an object in a fluid is a function of the viscosity of that fluid. They measure the torque required to rotate a disk or bob in a fluid at a known speed.

'Cup and bob' viscometers work by defining the exact volume of a sample which is to be sheared within a test cell; the torque required to achieve a certain rotational speed is measured and plotted. There are two classical geometries in "cup and bob" viscometers, known as either the "Couette" or "Searle" systems - distinguished by whether the cup or bob rotates. The rotating cup is preferred in some cases because it reduces the onset of Taylor vortices, but is more difficult to measure accurately.

'Cone and Plate' viscometers use a cone of very shallow angle in bare contact with a flat plate. With this system the shear rate beneath the plate is constant to a modest degree of precision and deconvolution of a flow curve; a graph of shear stress (torque) against shear rate (angular velocity) yields the viscosity in a straightforward manner.

Electromagnetically Spinning Sphere Viscometer (EMS Viscometer)

File:EMS viscometer measuring principle.png

Measuring Principle of the Electromagnetically Spinning Sphere Viscometer

The EMS Viscometer measures the viscosity of liquids through observation of the rotation of a sphere which is driven by electromagnetic interaction: Two magnets attached to a rotor create a rotating magnetic field. The sample (3) to be measured is in a small test tube (2). Inside the tube is an aluminium sphere (4). The tube is located in a temperature controlled chamber (1) and set such that the sphere is situated in the centre of the two magnets. The rotating magnetic field induces eddy currents in the sphere. The resulting Lorentz interaction between the magnetic field and these eddy currents generate torque that rotates the sphere. The rotational speed of the sphere depends on the rotational velocity of the magnetic field, the magnitude of the magnetic field and the viscosity of the sample around the sphere. The motion of the sphere is monitored by a video camera (5) located below the cell. The torque applied to the sphere is proportional to the difference in the angular velocity of the magnetic field Ω_B and the one of the sphere Ω_S. There is thus a linear relationship between (Ω_B−Ω_S)/Ω_S and the viscosity of the liquid.

This new measuring principle was developed by Sakai et al. at the University of Tokyo. The EMS viscometer distinguishes itself from other rotational viscometers by three main characteristics:

• All parts of the viscometer which come in direct contact with the sample are disposable and inexpensive.
• The measurements are performed in a sealed sample vessel.
• The EMS Viscometer requires only very small sample quantities (0.3 mL).

Stabinger viscometer

By modifying the classic Couette rotational viscometer, an accuracy comparable to that of kinematic viscosity determination is achieved. The internal cylinder in the Stabinger Viscometer is hollow and specifically lighter than the sample, thus floats freely in the sample, centered by centrifugal forces. The formerly inevitable bearing friction is thus fully avoided. The speed and torque measurement is implemented without direct contact by a rotating magnetic field and an eddy current brake. This allows for a previously unprecedented torque resolution of 50 pN·m and an exceedingly large measuring range from 0.2 to 20,000 mPa·s with a single measuring system. A built-in density measurement based on the oscillating U-tube principle allows the determination of kinematic viscosity from the measured dynamic viscosity employing the relation

\[ \nu = \frac {\eta} {\rho} \]

The Stabinger Viscometer was presented for the first time by Anton Paar GmbH at the ACHEMA in the year 2000. The measuring principle is named after its inventor Dr. Hans Stabinger.

Bubble viscometer

Bubble viscometers are used to quickly determine kinematic viscosity of known liquids such as resins and varnishes. The time required for an air bubble to rise is directly proportional to the viscosity of the liquid, so the faster the bubble rises, the lower the viscosity. The Alphabetical Comparison Method uses 4 sets of lettered reference tubes, A5 through Z10, of known viscosity to cover a viscosity range from 0.005 to 1,000 stokes. The Direct Time Method uses a single 3-line times tube for determining the "bubble seconds", which may then be converted to stokes.

Micro-Slit Viscometers

Viscosity measurement using flow through a slit dates back to 1838 when Mr. Jean Louis Marie Poiseuille conducted experiments to characterize the liquid flow through a pipe. He found that a viscous flow through a circular pipe requires pressure to overcome the wall shear stress. That was the birth of Hagen-Poiseuille flow equation. The slit viscometer geometry has flows analogous to the cylindrical pipe but has the additional advantage that no entrance or exit pressure drop corrections are needed. Detailed information regarding the implementation of this principal with modern MEMS and microfluidic science is further explained in a paper by RheoSense, Inc.

Generally, the slit viscosity technology offers the following advantages:

• Measures true (absolute) viscosity for both Newtonian and non-Newtonian fluids
• Enclosed system eliminates air interface and sample evaporation effects
• Measurements can be made using very small sample volumes
• Laminar flow even at high shear rates due to low Reynolds number
• Slit flow simulates real application flow conditions like drug injection or inkjetting.

Miscellaneous viscometer types

Other viscometer types use balls or other objects. Viscometers that can characterize non-Newtonian fluids are usually called rheometers or plastometers.

In the I.C.I "Oscar" viscometer, a sealed can of fluid was oscillated torsionally, and by clever measurement techniques it was possible to measure both viscosity and elasticity in the sample.

The Marsh funnel viscometer measures viscosity from the time (efflux time) it takes a known volume of liquid to flow from the base of a cone through a short tube. This is similar in principle to the flow cups (efflux cups) like the Ford, Zahn and Shell cups which use different shapes to the cone and various nozzle sizes. The measurements can be done according to ISO 2431, ASTM D1200 - 10 or DIN 53411.

See also

• Flow measurement
• Poiseuille equation
• Viscosity control
• Viscotherm

References

• British Standards Institute BS ISO/TR 3666:1998 Viscosity of water
• British Standards Institute BS 188:1977 Methods for Determination of the viscosity of liquids

External links

• ASTM International (ASTM D7042)
• Viscosity conversion tables[[es:yoi0-; omuhijd['] ]]