Isobutane

{{#if:OdorlessOdorlessColorless gas2.51 mg mL⁻¹ (at 15 °C, 100 kPa)204.8 kPa (at 21 °C)8.6 nmol Pa⁻¹ kg⁻¹40240104|! style="background: #F8EABA; text-align: center;" colspan="2" | Properties

Isobutane
Skeletal formula of isobutane
Skeletal formula of isobutane with all implicit carbons shown, and all explicit hydrogens added
Ball and stick model of isobutane	Spacefill model of isobutane
IUPAC name 2-Methylpropane
Identifiers
CAS number	75-28-5 7pxY
PubChem	6360
ChemSpider	6120 7pxY
UNII	BXR49TP611 7pxY
EC number	200-857-2
UN number	1969
KEGG	D04623 7pxY
ChEBI	CHEBI:30363 7pxY
RTECS number	TZ4300000
Beilstein Reference	1730720
Gmelin Reference	1301
Jmol-3D images	Image 1
SMILES CC(C)C <p><p style="word-wrap: break-word;">
InChI InChI=1S/C4H10/c1-4(2)3/h4H,1-3H3 7pxY Key: NNPPMTNAJDCUHE-UHFFFAOYSA-N 7pxY
Molecular formula	C4H10
Molar mass	58.12 g mol−1
Thermochemistry
Std enthalpy of formation ΔfHo298	−134.8–−133.6 kJ mol−1
Std enthalpy of combustion ΔcHo298	−2.86959–−2.86841 MJ mol−1
Specific heat capacity, C	96.65 J K−1 mol−1
Hazards
MSDS	External MSDS
GHS pictograms	The flame pictogram in the Globally Harmonized System of Classification and Labelling of Chemicals (GHS)
GHS signal word	DANGER
GHS hazard statements	H220
GHS precautionary statements	P210
EU Index	601-004-00-0
EU classification	Flammable F+
R-phrases	R12
S-phrases	(S2), S16
NFPA 704	75px 4 1 0
Flash point	-83 °C
Autoignition temperature	460 °C
Explosive limits	1.4–8.3%
Related compounds
Related alkane	Isopentane
Supplementary data page
Structure and properties	n, εr, etc.
Thermodynamic data	Phase behaviour Solid, liquid, gas
Spectral data	UV, IR, NMR, MS
14pxY (verify) (what is: 10pxY/10pxN?) Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Isobutane, also known as methylpropane, is an isomer of butane. It is the simplest alkane with a tertiary carbon. Concerns with depletion of the ozone layer by freon gases have led to increased use of isobutane as a gas for refrigeration systems, especially in domestic refrigerators and freezers, and as a propellant in aerosol sprays. When used as a refrigerant or a propellant, isobutane is also known as R-600a. Some portable camp stoves use a mixture of isobutane with propane, usually 80:20. Isobutane is used as a feedstock in the petrochemical industry, for example in the synthesis of isooctane.
Its UN number (for hazardous substances see shipping) is UN 1969. Isobutane is the R group for the amino acid leucine.

Nomenclature

File:N&i-butane.png

Structures of the two isomers of butane

Isobutane is the trivial name retained by the International Union of Pure and Applied Chemistry (IUPAC) in its 1993 Recommendations for the Nomenclature of Organic Chemistry. Since the longest continuous chain in isobutane is only three carbon atoms, the systematic name is methylpropane. The position number (2-) is unnecessary because it is the only possibility in methylpropane.

Uses

• As a refrigerant.

The use in refrigerators started in 1993 when Greenpeace presented the Greenfreeze project with the German company Foron.

Blends of pure, dry "isobutane" (R-600a) (commercial term used to describe isobutane mixtures) have negligible ozone depletion potential and very low Global Warming Potential (having a value of 3.3 times the GWP of carbon dioxide) and can serve as a functional replacement for R-12, R-22, R-134a, and other chlorofluorocarbon or hydrofluorocarbon refrigerants in conventional stationary refrigeration and air conditioning systems.

• As a propellant for aerosol cans and foam products.

Safety Concerns

Reports surfaced in late 2009 suggesting the use of isobutane as a refrigerant in domestic refrigerators was potentially dangerous. Several explosions resulting from the isobutane leaking into the refrigerator cabinet and a spark from the electrical system have been reported in the United Kingdom. Although unclear how serious this could be, at the time this report came out it was estimated 300 million refrigerators worldwide use isobutane as a refrigerant.

Although these stories are only speculation, the use of a flammable gas as a refrigerant is quite dangerous and encompasses a great deal of risk. The normal risks a CFC or other toxic refrigerant would have when it escapes, are mainly related to depletion of breathable air and frosting at the point of escape. Isobutane has an explosion risk associated also (in addition to depletion of breathable air and frosting). This explosion risk is more dangerous directly to anyone in the vicinity should it accumulate and come into contact with any ignition source. To reduce the risk, the charge of refrigerators was reduced by more than 50% against R134a. The typical charge of a R600a freezer is 45g and of a refrigerator 20g. If 45g are lost at once, 1m³ of explosive gas can be created. The risk that all gas is lost outside in a short time is very low. For interior refrigeration applications, the R600a appliances should have a hidden condenser, so that the gas can not be lost. 20g is for example approximately 3-4 times the charge of a cigarette lighter. In Europe the limit is 150g for R600a appliances due to safety.

According to an MSDS (Material Safety Data Sheet) for isobutane, this gas should not be exposed to temperatures above 52 Celsius or 151 Fahrenheit while in a closed system such as a storage tank. The range of flammability also factors into safety of this substance as a refrigerant. Flammable ranges for isobutane are between 1.8% - 8.4% and this creates a hazard when a leak forms in the refrigeration system. Many sources of ignition may be nearby so the unit could possibly explode due to the gas leak and cause major damage, not to mention injuries or death to persons nearby. This will create a problem for refrigeration technicians if a leak is reported. The leak must be checked in open air or well ventilated environments and the technician could risk injury to themselves or others. In essence, the refrigeration unit would need full replacement in most cases.

Substitution of this refrigerant for motor vehicle air conditioning systems not originally designed for R600a is widely prohibited or discouraged, on the grounds that using flammable hydrocarbons in systems originally designed to carry non-flammable refrigerant presents a significant risk of fire or explosion.

Vendors and advocates of hydrocarbon refrigerants argue against such bans on the grounds that there have been very few such incidents relative to the number of vehicle air conditioning systems filled with hydrocarbons. One particular test was conducted by a professor at the University of New South Wales that unintentionally tested the scenario of a sudden and complete refrigerant loss into the passenger compartment followed by subsequent ignition. He and several others in the car sustained burns to their face, ears, and hands, and several observers received lacerations from the burst glass of the front passenger window.

External links

• International Chemical Safety Card 0901
• NIOSH Pocket Guide to Chemical Hazards
• IUPAC Nomenclature of Organic Chemistry (online version of the "Blue Book")
• Data from Cheméo

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