Dibutylamine
Dibutylamine[1][2] | |||
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File:Dibutylamine.svg | |||
N-Butylbutanamine | |||
Other names Di-n-butylamine, N-Butyl-1-butanamine | |||
Identifiers | |||
CAS number | 111-92-2 | ||
PubChem | 8148 | ||
ChemSpider | 7856 7px | ||
RTECS number | HR7780000 | ||
Jmol-3D images | Image 1 | ||
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Molecular formula | C8H19N | ||
Molar mass | 129.244 g/mol | ||
Appearance | colorless liquid with ammonia odor | ||
Density | 0.7670 g/cm3 at 20°C | ||
Melting point |
-62°C | ||
Boiling point |
159.6°C | ||
Solubility in water | 4.7 g/L | ||
Solubility | soluble in acetone, benzene; very soluble in ethanol, diethyl ether | ||
Vapor pressure | 0.34 kPa | ||
Acidity (pKa) | 11.25[3] | Thermochemistry | |
Std enthalpy of formation ΔfH |
-206.0 kJ·mol-1 (liquid) -156.6 kJ·mol-1 (gas) | ||
Specific heat capacity, C | 292.9 J·mol-1·K-1 (liquid) | ||
Hazards | |||
MSDS | Oxford University
|
EU Index | Harmful (Xn), Corrosive (C) |
Flash point | 47°C | ||
Explosive limits | 1.1 – 6% | ||
LD50 | 360 mg/kg (oral, rat) | ||
Related compounds | |||
Related compounds | Dimethylamine Diethylamine Dipropylamine Diisopropylamine | ||
14px (verify) (what is: 10px /10px ?) Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) | |||
Infobox references |
Dibutylamine is an amine in the form of colorless liquid. It is miscible with almost all common organic solvents, and has limited miscibility with water. It is flammable, toxic, and corrosive to the skin and eyes.[4]
Applications
In oilfield, it is often used as a corrosion inhibitor and in the manufacture of emulsifiers. It is also used as intermediate in the production of:
- pharmaceuticals
- agricultural chemicals
- dye intermediates
- printing inks
- paper
- leather
- textile and dye auxiliaries
- photographic chemicals
- plasticizers
- additives for fuels and lubricants
- flotation agents
- rubber accelerators
- curing agents for epoxy resins
- catalysts for polyurethane resins
Shelf life
Dibutylamine has an almost unlimited shelf life in unopened, original containers.
Safety
Direct contact results in burns and eye injury. Ingestion results in damage to the gastrointestinal tract. Inhalation of vapors may irritate the respiratory tract. Inhalation may be fatal as a result of spasms, inflammation and edema of the larynx and bronchi.Overexposure may result in sensitization.
IR spectrum
References
- ↑ Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), Boca Raton, FL: CRC Press, pp. 3-160, 5-54, 8-53, 8-112, 15-18, 16-27, ISBN 0-8493-0594-2
- ↑ "Safety (MSDS) data for di-N-propylamine". Oxford University. http://msds.chem.ox.ac.uk/DI/di-N-propylamine.html. Retrieved 2009-04-07.
- ↑ Hall, H.K., J. Am. Chem. Soc., 1957, 79, 5441.
- ↑ Script error